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排序方式: 共有312条查询结果,搜索用时 31 毫秒
91.
Ana de Santiago-Martín Inmaculada Valverde-Asenjo Jose R. Quintana Antonio Vázquez Antonio L. Lafuente Concepción González-Huecas 《Environmental science and pollution research international》2013,20(9):6392-6405
A set of periurban calcareous agricultural Mediterranean soils was spiked with a mixture of Cd, Cu, Pb and Zn at two levels within the limit values proposed by current European legislation, incubated for up to 12 months, and subjected to various one-step extraction procedures to estimate mobile (neutral salts) and potentially mobile metal fractions (complexing and acidic extraction methods). The results obtained were used to study metal extractability patterns according to the soil characteristics. The analytical data were coupled with mineralogical investigations and speciation modelling using the Visual Minteq model. The formation of soluble metal-complexes in the complexing extracts (predicted by the Visual Minteq calculations) led to the highest extraction efficiency with complexing extractants. Metal extractability patterns were related to both content and composition of carbonate, organic matter, Fe oxide and clay fractions. Potentially mobile metal fractions were mainly affected by the finest soil fractions (recalcitrant organic matter, active lime and clay minerals). In the case of Pb, scarce correlations between extractable Pb and soil constituents were obtained which was attributed to high Pb retention due to the formation of 4PbCO3·3PbO (corroborated by X-ray diffraction). In summary, the high metal proportion extracted with complexing agents highlighted the high but finite capacity to store potentially mobilizable metals and the possible vulnerability of these soils against environmental impact from metal accumulation. 相似文献
92.
Céline Dupont Francesca Romana Grati Kwong Wai Choy Sylvie Jaillard Jérôme Toutain Marie-Laure Maurin Jose Antonio Martínez-Conejero Claire Beneteau Aurélie Coussement Denise Molina-Gomes Nina Horelli-Kuitunen Azzedine Aboura Anne-Claude Tabet Justine Besseau-Ayasse Bettina Bessieres-Grattagliano Giuseppe Simoni Gustavo Ayala Brigitte Benzacken François Vialard 《黑龙江环境通报》2015,35(1):35-43
93.
Gomez-Eyles JL Collins CD Hodson ME 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):918-923
Validating chemical methods to predict bioavailable fractions of polycyclic aromatic hydrocarbons (PAHs) by comparison with accumulation bioassays is problematic. Concentrations accumulated in soil organisms not only depend on the bioavailable fraction but also on contaminant properties. A historically contaminated soil was freshly spiked with deuterated PAHs (dPAHs). dPAHs have a similar fate to their respective undeuterated analogues, so chemical methods that give good indications of bioavailability should extract the fresh more readily available dPAHs and historic more recalcitrant PAHs in similar proportions to those in which they are accumulated in the tissues of test organisms. Cyclodextrin and butanol extractions predicted the bioavailable fraction for earthworms (Eisenia fetida) and plants (Lolium multiflorum) better than the exhaustive extraction. The PAHs accumulated by earthworms had a larger dPAH:PAH ratio than that predicted by chemical methods. The isotope ratio method described here provides an effective way of evaluating other chemical methods to predict bioavailability. 相似文献
94.
95.
Air-vegetation transfer of PCDD/PCDFs: an assessment of field data and implications for modeling 总被引:1,自引:0,他引:1
Schuhmacher M Jones KC Domingo JL 《Environmental pollution (Barking, Essex : 1987)》2006,142(1):143-150
This study was designed to evaluate soil and air (gas and particle) transfer of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) to vegetation in residential and industrial areas. In a first part, soil-vegetation transfer was assessed. The levels of PCDD/Fs in 120 soil and 120 herbage samples collected from 1996 to 2002 in an industrial area of Montcada (Barcelona, Spain), near a municipal solid waste incinerator (MSWI), were determined. Some additional individual samples were also evaluated. It was concluded that high soil concentrations, which are not at steady state with the air layer above it, show a tendency for PCDD/Fs to escape via volatilization. In a second part of the study, air-vegetation transfer was examined. PCDD/F concentrations from 24 herbage samples were used, while PCDD/F concentrations were also measured in seven high-volume air samples and seven passive air-vapor samples. Scavenging coefficients (m3 air "sampled"/g grass d.m.) ranged from 1.9 to 11.3 m3/g. A good trend with K(OA) was observed for PCDDs (R=0.82), while it was lower for PCDFs (R=0.55). The current results corroborate that PCDD/F concentrations in vegetation are associated with atmospheric deposition. For the highest substituted PCDD/F congeners, the air-particle uptake from plants is the principal pathway. In regions impacted by combustion emission sources, PCDD/F gas-particle partitioning is influenced by a higher concentration of particles in the air. Particles and associated particle-bound PCDD/Fs would sorb to leaf surfaces, and are subject to removal via wash off. However, in areas where emissions to air are not very notable, vapor absorption would be the principal source of vegetation pollution. The results of this investigation can have a potential interest in risk assessment studies and environmental fate models. 相似文献
96.
Rohit Sati Elizabeth M Crown Mark Ackerman Jose Gonzalez Douglas Dale 《International journal of occupational safety and ergonomics》2008,14(1):29-41
Extensive use of pressurized steam in the oil and gas sectors has led to incidents where workers were seriously injured. In this study a test device and procedure to measure heat transfer through fabrics during steam exposure were developed and evaluated. Several factors were considered while designing the test device to simulate work site conditions. Fabrics were exposed to steam at 2 distances (50 and 100 mm) and 2 pressures (207 and 69 kPa). Theoretical considerations included heat and mass transfer, and fabric structure and performance properties. The test device and procedure differentiated well among both fabrics and exposure conditions. For all fabrics, maximum heat transfer was observed at highest steam pressure and shortest distance. Laminated and coated fabrics performed better than a fabric without such treatments. 相似文献
97.
Barcelo-Quintal MH Cebada-Ricalde MC Trejo-Irigoyen AR Rendon-Osorio RB Manzanilla-Cano JA 《Journal of environmental science and health. Part. B》2008,43(2):120-126
Kinetic studies of endosulfan photochemical degradation in controlled aqueous systems were carried out by ultraviolet light irradiation at lambda = 254 nm. The photolysis of (alpha + beta: 2 + 1) endosulfan, alpha-endosulfan and beta-endosulfan were first-order kinetics. The observed rate constants obtained from linear least-squares analysis of the data were 1 x 10(-4) s(-1); 1 x 10(-4) s(-1); and 2 x 10(-5) s(-1), respectively, and the calculated quantum yields (phi) were 1, 1 and 1.6, respectively. Preliminary differential pulse polarographic (DPP) analysis allowed to observe the possible endosulfan photochemical degradation pathway. This degradation route involves the formation of the endosulfan diol, its transformation to endosulfan ether and finally the ether's complete degradation by observing the potential shifts. 相似文献
98.
Charbel Jose Chiappetta Jabbour 《Journal of Cleaner Production》2010,18(12):1222-1225
A study was conducted to verify whether the theory on the evolution of corporate environmental management (CEM) is applicable to organizations located in Brazil. Some of the most important proposals pertaining to the evolution of CEM were evaluated in a systematic fashion and integrated into a typical theoretical framework containing three evolutionary stages: reactive, preventive and proactive. The validity of this framework was tested by surveying 94 companies located in Brazil with ISO 14001 certification. Results indicated that the evolution of CEM tends to occur in a manner that is counter to what has generally been described in the literature. Two evolutionary stages were identified: 1) synergy for eco-efficiency and 2) environmental legislation view, which combine variables that were initially categorized into different theoretical CEM stages. These data, obtained from a direct study of Brazilian companies, suggest that the evolution of environmental management in organizations tends to occur in a non-linear fashion, requiring a re-analysis of traditional perceptions of CEM development, as suggested by Kolk and Mauser (2002). 相似文献
99.
100.
The clearing of forests to obtain land for pasture and agriculture and the replacement of autochthonous species by other faster-growing varieties of trees for timber have both led to the loss of vast areas of forest worldwide. At present, many developed countries are attempting to reverse these effects, establishing policies for the restoration of older woodland systems. Reforestation is a complex matter, planned and carried out by experts who need objective information regarding the type of forest that can be sustained in each area. This information is obtained by drawing up feasibility models constructed using statistical methods that make use of the information provided by morphological and environmental variables (height, gradient, rainfall, etc.) that partially condition the presence or absence of a specific kind of forestation in an area. The aim of this work is to construct a set of feasibility models for woodland located in the basin of the River Liébana (NW Spain), to serve as a support tool for the experts entrusted with carrying out the reforestation project. The techniques used are multilayer perceptron neural networks and support vector machines. Their results will be compared to the results obtained by traditional techniques (such as discriminant analysis and logistic regression) by measuring the degree of fit between each model and the existing distribution of woodlands. The interpretation and problems of the feasibility models are commented on in the Discussion section. 相似文献